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n-Butyllithium, 2.5M solution in hexanes, AcroSeal™, Thermo Scientific Chemicals

CAS: 109-72-8 Molecular Formula: C4H9Li Molecular Weight (g/mol): 64.06 MDL Number: MFCD00009414 InChI Key: MZRVEZGGRBJDDB-UHFFFAOYSA-N Synonym: n-butyllithium,lithium, butyl,butyllithium,butyl lithium,n-butyl lithium,lithium butane,n-buli,buli,libu,unii-09w9a6b8zc PubChem CID: 61028 SMILES: [Li]CCCC

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Organic lithium salts

PubChem CID	61028
CAS	109-72-8
Molecular Weight (g/mol)	64.06
MDL Number	MFCD00009414
SMILES	[Li]CCCC
Synonym	n-butyllithium,lithium, butyl,butyllithium,butyl lithium,n-butyl lithium,lithium butane,n-buli,buli,libu,unii-09w9a6b8zc
InChI Key	MZRVEZGGRBJDDB-UHFFFAOYSA-N
Molecular Formula	C4H9Li

n-Butyllithium, 1.6M solution in hexanes, AcroSeal™, Thermo Scientific Chemicals

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Organic lithium salts

PubChem CID	61028
CAS	109-72-8
Molecular Weight (g/mol)	64.06
MDL Number	MFCD00009414
SMILES	[Li]CCCC
Synonym	n-butyllithium,lithium, butyl,butyllithium,butyl lithium,n-butyl lithium,lithium butane,n-buli,buli,libu,unii-09w9a6b8zc
InChI Key	MZRVEZGGRBJDDB-UHFFFAOYSA-N
Molecular Formula	C4H9Li

Lithium aluminum Hydride, 2.4M Solution in THF, AcroSeal™, Thermo Scientific Chemicals

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Linear Formula	LiAlH₄
Molecular Weight (g/mol)	37.95
UN Number	1411
InChI Key	OCZDCIYGECBNKL-UHFFFAOYSA-N
Density	0.9000g/mL
PubChem CID	21226445
Name Note	2.4M Solution in THF
Percent Purity	9.2 to 10.5% (as LiAlH4)
Formula Weight	37.95
Color	Yellow
Physical Form	Viscous Liquid
Chemical Name or Material	Lithium Aluminum hydride
SMILES	[Li+].[AlH4-]
Merck Index	15, 344
Concentration	9.5 to 10.5% (as LiAlH4)
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
MDL Number	MFCD00011075
Health Hazard 2	GHS H Statement In contact with water releases flammable gases which may ignite spontaneously. Highly flammable liquid and vapor. Causes severe skin burns and eye damage. May cause respiratory irritation. May form explosive peroxides. Suspected of causing cancer. Harmful if swallowed. May cause drowsiness or dizziness.
Flash Point	−17°C
Solubility Information	Solubility in water: vigorous reaction.
Health Hazard 1	Danger
Synonym	lithium aluminum hydride,lithium aluminum hydride,aluminum lithium hydride,lithiumaluminiumhydride,aluminum iii lithium hydride,lithium alanate,lithium aluminum tetrahydride,lithiumaluminiumhydrid,litiumaluminum hydride,lithim aluminum hydride
IUPAC Name	aluminum;lithium;hydride
Molecular Formula	AlH4Li
Specific Gravity	0.9

hydrogen chloride, 4N solution in 1,4-dioxane, AcroSeal™, Thermo Scientific Chemicals

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Linear Formula	HCl
Molecular Weight (g/mol)	36.46
ChEBI	CHEBI:17883
InChI Key	VEXZGXHMUGYJMC-UHFFFAOYSA-N
Density	1.0500g/mL
PubChem CID	313
Name Note	4N solution in 1, 4-dioxane
Formula Weight	36.45
Color	Colorless to White
Physical Form	Crystals or Crystalline Powder
Chemical Name or Material	Hydrochloric acid
SMILES	Cl
Merck Index	14, 4794
Concentration	3.95 to 4.40N
CAS	123-91-1
Health Hazard 3	GHS P Statement: Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. Use personal protective equipment as required. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Avoid breathing dust/fume/gas/mist/vapors/spray. Keep container tightly closed. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment. WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.
MDL Number	MFCD00011324 MFCD00792839
Health Hazard 2	GHS H Statement: Causes severe skin burns and eye damage. Suspected of causing cancer. Toxic if inhaled. Highly flammable liquid and vapor. May form explosive peroxides. Repeated exposure may cause skin dryness or cracking.
Flash Point	17°C
Packaging	AcroSeal™ Glass Bottle
Solubility Information	Solubility in water: soluble. Other solubilities: soluble in most organic solvents
Health Hazard 1	Danger
Synonym	hydrochloric acid,hydrogen chloride,muriatic acid,chlorohydric acid,acide chlorhydrique,chlorwasserstoff,spirits of salt,hydrogen chloride hcl,anhydrous hydrochloric acid,chloorwaterstof
IUPAC Name	hydrogen chloride
Molecular Formula	ClH
Specific Gravity	1.05

Borane-tetrahydrofuran complex, 1M solution in THF, Stabilized, AcroSeal™, Thermo Scientific Chemicals

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Molecular Weight (g/mol)	85.94
InChI Key	RMCYTHFAWCWRFA-UHFFFAOYSA-N
Density	0.8760g/mL
Treatment(s)	Stabilized
PubChem CID	11062302
Name Note	1M solution in tetrahydrofuran, stabilized
Fieser	01,199; 02,106; 03,76; 04,124; 05,184; 06,161; 07,89; 12,65; 17,101
Formula Weight	85.94
Color	Colorless
Physical Form	Liquid
Chemical Name or Material	Borane-tetrahydrofuran complex
SMILES	B.C1CCOC1
Merck Index	15, 1336
Concentration	0.96 to 1.08M
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
MDL Number	MFCD00012429
Health Hazard 2	GHS H Statement May cause respiratory irritation. Causes serious eye damage. In contact with water releases flammable gases which may ignite spontaneously. Causes skin irritation. Harmful if swallowed. Highly flammable liquid and vapour. Suspected of causing cancer. Reacts violently with water. May form explosive peroxides. May cause drowsiness or dizziness.
Flash Point	−22°C
Packaging	AcroSeal™ Glass bottle
Solubility Information	Solubility in water: reacts.
Health Hazard 1	Danger
Synonym	borane-tetrahydrofuran complex,tetrahydrofuran borane,bh3.thf,borane tetrahydrofuran complex solution,borane-d3-thf complex solution,borane-tetrahydrofuran,unii-5ear4err1l,oxolane borane,boron; oxolane,borane thf
TSCA	TSCA
IUPAC Name	oxolane borane
Molecular Formula	C4H11BO
EINECS Number	237-881-8
Specific Gravity	0.876

Lithium diisopropylamide, 2M sol. in THF/n-heptane/ethylbenzene, AcroSeal™, Thermo Scientific Chemicals

CAS: 4111-54-0 Molecular Formula: C6H14LiN Molecular Weight (g/mol): 107.125 MDL Number: MFCD00064449 InChI Key: ZCSHNCUQKCANBX-UHFFFAOYSA-N Synonym: lithium diisopropylamide,unii-ol028kiw1i,lithium di-isopropylamide,lithium diisopropyl amide,2-propanamine, n-1-methylethyl-, lithium salt,ol028kiw1i,lithium di propan-2-yl azanide,2-propanamine, n-1-methylethyl-, lithium salt 1:1,lithium n,n-diisopropylamide,ipr2nli PubChem CID: 2724682 IUPAC Name: lithium;di(propan-2-yl)azanide SMILES: [Li+].CC(C)[N-]C(C)C

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PubChem CID	2724682
CAS	4111-54-0
Molecular Weight (g/mol)	107.125
MDL Number	MFCD00064449
SMILES	[Li+].CC(C)[N-]C(C)C
Synonym	lithium diisopropylamide,unii-ol028kiw1i,lithium di-isopropylamide,lithium diisopropyl amide,2-propanamine, n-1-methylethyl-, lithium salt,ol028kiw1i,lithium di propan-2-yl azanide,2-propanamine, n-1-methylethyl-, lithium salt 1:1,lithium n,n-diisopropylamide,ipr2nli
IUPAC Name	lithium;di(propan-2-yl)azanide
InChI Key	ZCSHNCUQKCANBX-UHFFFAOYSA-N
Molecular Formula	C6H14LiN

Ammonia, ca. 7N solution in methanol, AcroSeal™, Thermo Scientific Chemicals

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Linear Formula	NH₃
Molecular Weight (g/mol)	17.03
ChEBI	CHEBI:16134
Color	Colorless to Yellow
Physical Form	Liquid
Chemical Name or Material	Ammonia
SMILES	N
Merck Index	15, 488
Concentration	6.0 to 7.5N
InChI Key	QGZKDVFQNNGYKY-UHFFFAOYSA-N
Density	0.7700g/mL
PubChem CID	222
Name Note	7N solution in methanol
CAS	67-56-1
Health Hazard 3	GHS P Statement: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Wear protective gloves/protective clothing/eye protection/face protection. Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Gently wash with plenty of soap and water. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF exposed: Call a POISON CENTER or doctor/physician. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Avoid release to the environment. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment. WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.
MDL Number	MFCD00011418
Health Hazard 2	GHS H Statement: Toxic if swallowed. Causes severe skin burns and eye damage. Toxic in contact with skin. Causes damage to organs. Fatal if inhaled. Highly flammable liquid and vapor.
Flash Point	14°C
Packaging	AcroSeal™ Glass Bottle
Health Hazard 1	GHS Signal Word: Danger
Synonym	ammonia,ammonia gas,spirit of hartshorn,nitro-sil,ammoniakgas,ammonia anhydrous,anhydrous ammonia,ammonia, anhydrous,ammoniak,am-fol
IUPAC Name	azane
Molecular Formula	H3N
Formula Weight	17.03
Specific Gravity	0.77

Diisopropylamine, 99.5%, redistilled, AcroSeal™, Thermo Scientific Chemicals

CAS: 108-18-9 Molecular Formula: C₆H₁₅N Molecular Weight (g/mol): 101.19 MDL Number: MFCD00008862 InChI Key: UAOMVDZJSHZZME-UHFFFAOYSA-N Synonym: diisopropylamine,2-propanamine, n-1-methylethyl,n-1-methylethyl-2-propanamine,dipa,n,n-diisopropylamine,bis propan-2-yl amine,n-isopropylpropan-2-amine,di-isopropylamine,n-isopropyl-1-amino-2-methylethane,diisopropyl amine PubChem CID: 7912 IUPAC Name: N-propan-2-ylpropan-2-amine SMILES: CC(C)NC(C)C

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Secondary amines

PubChem CID	7912
CAS	108-18-9
Molecular Weight (g/mol)	101.19
MDL Number	MFCD00008862
SMILES	CC(C)NC(C)C
Synonym	diisopropylamine,2-propanamine, n-1-methylethyl,n-1-methylethyl-2-propanamine,dipa,n,n-diisopropylamine,bis propan-2-yl amine,n-isopropylpropan-2-amine,di-isopropylamine,n-isopropyl-1-amino-2-methylethane,diisopropyl amine
IUPAC Name	N-propan-2-ylpropan-2-amine
InChI Key	UAOMVDZJSHZZME-UHFFFAOYSA-N
Molecular Formula	C₆H₁₅N

tert-Butyllithium, 1.9M solution in pentane, AcroSeal™, Thermo Scientific Chemicals

CAS: 594-19-4 Molecular Formula: C4H9Li Molecular Weight (g/mol): 64.06 MDL Number: MFCD00008795 InChI Key: BKDLGMUIXWPYGD-UHFFFAOYSA-N Synonym: tert-butyllithium,t-butyllithium,tbuli,lithium, 1,1-dimethylethyl,t-buli,lithium 2-methylpropane,tert-butyllithium solution,tert butyllithium,t-butyllithiurn PubChem CID: 638178 SMILES: [Li]C(C)(C)C

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Organic lithium salts

PubChem CID	638178
CAS	594-19-4
Molecular Weight (g/mol)	64.06
MDL Number	MFCD00008795
SMILES	[Li]C(C)(C)C
Synonym	tert-butyllithium,t-butyllithium,tbuli,lithium, 1,1-dimethylethyl,t-buli,lithium 2-methylpropane,tert-butyllithium solution,tert butyllithium,t-butyllithiurn
InChI Key	BKDLGMUIXWPYGD-UHFFFAOYSA-N
Molecular Formula	C4H9Li

Boron trifluoride etherate, ca. 48% BF3, AcroSeal™, Thermo Scientific Chemicals

CAS: 109-63-7 Molecular Formula: C4H10BF3O Molecular Weight (g/mol): 141.93 MDL Number: MFCD00013194 InChI Key: KZMGYPLQYOPHEL-UHFFFAOYSA-N Synonym: Boron trifluoride ethyl ether PubChem CID: 8000 IUPAC Name: ethoxyethane;trifluoroborane SMILES: FB(F)F.CCOCC

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Enediols

PubChem CID	8000
CAS	109-63-7
Molecular Weight (g/mol)	141.93
MDL Number	MFCD00013194
SMILES	FB(F)F.CCOCC
Synonym	Boron trifluoride ethyl ether
IUPAC Name	ethoxyethane;trifluoroborane
InChI Key	KZMGYPLQYOPHEL-UHFFFAOYSA-N
Molecular Formula	C4H10BF3O

sec-Butyllithium, 1.3M sol. in cyclohexane/hexane (92/8), AcroSeal™, Thermo Scientific Chemicals

CAS: 598-30-1 Molecular Formula: C4H9Li Molecular Weight (g/mol): 64.06 MDL Number: MFCD00009323 InChI Key: VATDYQWILMGLEW-UHFFFAOYNA-N Synonym: sec-butyllithium,s-buli,s-butyllithium,s-butyl lithium,unii-5yv3gii1tb,lithium, 1-methylpropyl,5yv3gii1tb,secbutyllithium,b-butyllithium,sec-butyllitium PubChem CID: 102446 IUPAC Name: (butan-2-yl)lithium SMILES: [Li]C(C)CC

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General Chemistry Solutions

PubChem CID	102446
CAS	598-30-1
Molecular Weight (g/mol)	64.06
MDL Number	MFCD00009323
SMILES	[Li]C(C)CC
Synonym	sec-butyllithium,s-buli,s-butyllithium,s-butyl lithium,unii-5yv3gii1tb,lithium, 1-methylpropyl,5yv3gii1tb,secbutyllithium,b-butyllithium,sec-butyllitium
IUPAC Name	(butan-2-yl)lithium
InChI Key	VATDYQWILMGLEW-UHFFFAOYNA-N
Molecular Formula	C4H9Li

Diisobutylaluminium hydride, 1.2M (20 wt%) solution in toluene, AcroSeal™, Thermo Scientific Chemicals

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Organoaluminum

Boiling Point	110.0°C
Linear Formula	[(CH₃)₂CHCH₂]₂AIH
Molecular Weight (g/mol)	142.22
Physical Form	Solution
Chemical Name or Material	Diisobutylaluminium hydride
Merck Index	15, 3212
Density	0.8480g/mL
Fieser	01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS	108-88-3
Health Hazard 3	GHS P Statement IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsi
MDL Number	MFCD00008928
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. May be fatal if swallowed and enters airways. May cause damage to organs through prolonged or repeated exposure. Suspected of damaging the unborn child. May cause dro
Solubility Information	Solubility in water: reacts violently. Other solubilities: miscible with saturated aliphatic and aromatic,hydrocarbons
Flash Point	4°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	DIBAL-H
Beilstein	04, IV, 4400
Molecular Formula	C₈H₁₉Al
EINECS Number	214-729-9
Formula Weight	142.22
Specific Gravity	0.848

Tetrabutylammonium fluoride, 1M solution in THF, AcroSeal™, Thermo Scientific Chemicals

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Ammonium Salts

Linear Formula	[CH₃(CH₂)₃]₄NF
Molecular Weight (g/mol)	261.47
ChEBI	CHEBI:51990
Color	Brown to Green
Physical Form	Solution
SMILES	[F-].CCCC[N+](CCCC)(CCCC)CCCC
Merck Index	15,9332
InChI Key	FPGGTKZVZWFYPV-UHFFFAOYSA-M
Density	0.8870g/mL
PubChem CID	2724141
Concentration or Composition (by Analyte or Components)	0.90 to 1.10M
CAS	7732-18-5
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wear protective gloves/protective clothing/eye p
MDL Number	MFCD00011747
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation. Highly flammable liquid and vapor. May form explosive peroxides. May cause drowsiness or dizzines
Flash Point	−17°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	tetrabutylammonium fluoride,tbaf,tetrabutylazanium fluoride,tetrabutyl ammonium fluoride,tetra-n-butylammonium fluoride,tetrabutylamine, fluoride,n,n,n-tributylbutan-1-aminium fluoride,1-butanaminium, n,n,n-tributyl-, fluoride,n,n,n-tributyl-1-butanaminium fluoride,1-butanaminium, n,n,n-tributyl-, fluoride 1:1
IUPAC Name	tetrabutylazanium;fluoride
Molecular Formula	C16H36FN
EINECS Number	207-057-2
Formula Weight	261.46
Specific Gravity	0.887

Diisobutylaluminium hydride, 1M solution in hexane, AcroSeal™, Thermo Scientific Chemicals

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Organoaluminum

Linear Formula	[(CH₃)₂CHCH₂]₂AlH
Molecular Weight (g/mol)	142.22
Physical Form	Solution
Chemical Name or Material	Diisobutylaluminium hydride
Merck Index	15, 3212
Density	0.7010g/mL
Name Note	1M Solution in Hexane
Fieser	01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS	110-54-3
Health Hazard 3	GHS P Statement IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective g
MDL Number	MFCD00008928
Health Hazard 2	GHS H Statement May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. May cause damage to organs through p
Solubility Information	Solubility in water: reacts
Flash Point	−23°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	DIBAL-H
Beilstein	04, IV, 4400
Molecular Formula	C₈H₁₉Al
EINECS Number	214-729-9
Formula Weight	142.22
Specific Gravity	0.701
Melting Point	-70.0°C

Boron tribromide, 1M solution in methylene chloride, AcroSeal™, Thermo Scientific Chemicals

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Metalloid Salts

Linear Formula	BBr₃
Molecular Weight (g/mol)	250.52
Chemical Name or Material	Boron tribromide
SMILES	BrB(Br)Br
Merck Index	15,1349
InChI Key	ILAHWRKJUDSMFH-UHFFFAOYSA-N
Density	1.4670g/mL
PubChem CID	25134
CAS	75-09-2
Health Hazard 3	GHS P Statement IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wear protective gloves/protective clothing/eye protection/face protection.
MDL Number	MFCD00011312
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. Fatal if inhaled. Fatal if swallowed. Suspected of causing cancer. Reacts violently with water. May cause drowsiness or dizziness.
Packaging	AcroSeal™ Glass bottle
Solubility Information	Solubility in water: reacts. Other solubilities: decomposes in alcohol, soluble in alcohol and ccl4
Health Hazard 1	GHS Signal Word: Danger
Synonym	boron tribromide,borane, tribromo,boron bromide,tribromoboron,hsdb 327,tribromoboran,boron tribrornide,boron tri bromide,boron tri-bromide
IUPAC Name	tribromoborane
Molecular Formula	BBr3
EINECS Number	233-657-9
Formula Weight	250.52
Specific Gravity	1.467

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