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  7. Triethyl phosphonoacetate, 98+%, Thermo Scientific Chemicals

Triethyl phosphonoacetate, 98+%, Thermo Scientific Chemicals

Product Code. 11438086
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Description

Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.

Solubility
Slightly miscible with water.

Notes
Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 867-13-0
Molecular Formula C8H17O5P
Molecular Weight (g/mol) 224.193
MDL Number MFCD00009177
InChI Key GGUBFICZYGKNTD-UHFFFAOYSA-N
Synonym triethyl phosphonoacetate, ethyl 2-diethoxyphosphoryl acetate, ethyl diethoxyphosphoryl acetate, ethyl diethylphosphono acetate, triethyl phosphonoethanoate, diethyl carboethoxymethylphosphonate, diethyl ethoxycarbonylmethanephosphonate, diethylphosphonoacetic acid ethyl ester, diethyl carbethoxymethylphosphonate
PubChem CID 13345
IUPAC Name ethyl 2-diethoxyphosphorylacetate
SMILES CCOC(=O)CP(=O)(OCC)OCC

Specifications

Melting Point -24°C
Density 1.125
Boiling Point 260°C to 262°C
Flash Point 165°C (329°F)
Refractive Index 1.431
Quantity 100 g
Beilstein 1343714
Solubility Information Slightly miscible with water.
Formula Weight 224.19
Percent Purity ≥98%
Chemical Name or Material Triethyl phosphonoacetate
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