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  7. 2-(2-Bromoethyl)-1,3-dioxane, 98%, Thermo Scientific Chemicals

2-(2-Bromoethyl)-1,3-dioxane, 98%, Thermo Scientific Chemicals

Product Code. 11394384
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Quantity:
10 g
50 g
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This item is not returnable. View return policy

Description

2-(2-Bromoethyl)-1,3-dioxane, Provides a useful means of introducing a masked β-formylethyl group. In comparison with the corresponding dioxolane (following entry), the dioxane is more stable to acid, and the Grignard is thermally stable. Reaction of the Grignard with an acid chloride gives the ketone in high yield without further reaction to the tertiary alcohol. Subsequent hydrolysis of the 1,3-dioxane gives the -ketoaldehyde. It is also used as a pharmaceutical intermediate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-(2-Bromoethyl)-1,3-dioxane, Provides a useful means of introducing a masked ß-formylethyl group. In comparison with the corresponding dioxolane (following entry), the dioxane is more stable to acid, and the Grignard is thermally stable. Reaction of the Grignard with an acid chloride gives the ketone in high yield without further reaction to the tertiary alcohol. Subsequent hydrolysis of the 1,3-dioxane gives the -ketoaldehyde. It is also used as a pharmaceutical intermediate.

Solubility
It is not soluble in water but soluble in organic solvent such as ethanol.

Notes
Air, Heat sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 33884-43-4
Molecular Formula C6H11BrO2
Molecular Weight (g/mol) 195.06
MDL Number MFCD00006567
InChI Key KXMZOKKPQZRPRN-UHFFFAOYNA-N
Synonym 2-2-bromoethyl-1,3-dioxane, 1,3-dioxane, 2-2-bromoethyl, 3-bromopropionaldehyde trimethylene acetal, 2 2-bromoethyl-1,3-dioxane, 2-2-bromoethyl-1,3 dioxane, bromoethyl-1,3-dioxane, acmc-209i3o, 2-2-bromoetyl 1,3-dioxane, wmdhqehpovoeog-uhfffaoysa, 2-2-bromoethyl 1,3-dioxane
PubChem CID 520656
SMILES CC(Br)C1OCCCO1

Specifications

Density 1.434
Boiling Point 67°C to 70°C (3 mmHg)
Flash Point 96°C (204°F)
Refractive Index 1.482
Quantity 10 g
Beilstein 1421628
Solubility Information It is not soluble in water but soluble in organic solvent such as ethanol.
IUPAC Name 2-(2-bromoethyl)-1,3-dioxane
Formula Weight 195.06
Percent Purity 98%
Chemical Name or Material 2-(2-Bromoethyl)-1,3-dioxane
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